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Abstract Photothermal CO₂reduction is one of the most promising routes to efficiently utilize solar energy for fuel production at high rates. However, this reaction is currently limited by underdeveloped catalysts with low photothermal conversion efficiency, insufficient exposure of active sites, low active material loading, and high material cost. Herein, we report a potassium‐modified carbon‐supported cobalt (K⁺−Co−C) catalyst mimicking the structure of a lotus pod that addresses these challenges. As a result of the designed lotus‐pod structure which features an efficient photothermal C substrate with hierarchical pores, an intimate Co/C interface with covalent bonding, and exposed Co catalytic sites with optimized CO binding strength, the K⁺−Co−C catalyst shows a record‐high photothermal CO₂hydrogenation rate of 758 mmol g_cat⁻¹ h⁻¹(2871 mmol g_Co⁻¹ h⁻¹) with a 99.8 % selectivity for CO, three orders of magnitude higher than typical photochemical CO₂reduction reactions. We further demonstrate with this catalyst effective CO₂conversion under natural sunlight one hour before sunset during the winter season, putting forward an important step towards practical solar fuel production. 

Drones are increasingly used during routine inspections of bridges to improve data consistency, work efficiency, inspector safety, and cost effectiveness. Most drones, however, are operated manually within a visual line of sight and thus unable to inspect long-span bridges that are not completely visible to operators. In this paper, aerial nondestructive evaluation (aNDE) will be envisioned for elevated structures such as bridges, buildings, dams, nuclear power plants, and tunnels. To enable aerial nondestructive testing (aNDT), a human-robot system will be created to integrate haptic sensing and dexterous manipulation into a drone or a structural crawler in augmented/virtual reality (AR/VR) for beyond-visual-line-of-sight (BVLOS) inspection of bridges. Some of the technical challenges and potential solutions associated with aNDT&E will be presented. Example applications of the advanced technologies will be demonstrated in simulated bridge decks with stipulated conditions. The developed human-robot system can transform current on-site inspection to future tele-inspection, minimizing impact to traffic passing over the bridges. The automated tele-inspection can save as much as 75% in time and 95% in cost. 

Abstract We report a precious‐metal‐free molecular catalyst‐based photocathode that is active for aqueous CO 2 reduction to CO and methanol. The photoelectrode is composed of cobalt phthalocyanine molecules anchored on graphene oxide which is integrated via a (3‐aminopropyl)triethoxysilane linker to p‐type silicon protected by a thin film of titanium dioxide. The photocathode reduces CO 2 to CO with high selectivity at potentials as mild as 0 V versus the reversible hydrogen electrode (vs RHE). Methanol production is observed at an onset potential of −0.36 V vs RHE, and reaches a peak turnover frequency of 0.18 s −1 . To date, this is the only molecular catalyst‐based photoelectrode that is active for the six‐electron reduction of CO 2 to methanol. This work puts forth a strategy for interfacing molecular catalysts to p‐type semiconductors and demonstrates state‐of‐the‐art performance for photoelectrochemical CO 2 reduction to CO and methanol.